International Ocean Discovery Program Research Articles

The role of ice-sheet dynamics in the Miocene-Pliocene depositional systems of the Ross Sea, Antarctica

The dynamics of the Antarctic ice sheet (AIS) have profound implications for the evolution of the Antarctic continental margin, global ocean currents, and climate changes. Marine sediments from the Antarctic continental margins recorded the history of the advance and retreat of the AIS. In this study, we present an integrated analysis of the sedimentary characteristics of the Early Miocene to Late Miocene of the Ross Sea by using 2D seismic reflection data and cores from International Ocean Discovery Program (IODP) Expedition 374 Sites U1521, U1522, and U1524. The characteristics of the seismic facies and sediments show that the expansion and grounding of the ice sheets across the continental shelf significantly influenced the depositional processes, leading to increased glacial erosion, the formation of prograding wedges, mass transport deposits (MTDs), and mixed (turbidite-contourite) depositional systems since the Early Miocene. The seaward migration of the continental shelf edge and the steepening of the continental slope were mainly influenced by the glaciation of extreme expansion of the AIS. Marked increases in the prograding wedge and MTD are associated with extensive sediment reworking and deposition at the grounding zones and along the continental slope as a result of ice sheet expansion. The development of the mixed (turbidite-contourite) depositional systems was the result of extensive sediment reworking and deposition by gravity flows and bottom currents on the continental slope and the rise. This research provides new insights into the complexity of the ice sheet and the sensibility of marginal sediments in responding to the past climate changes in Antarctica.

New Insights Into the Surface‐Ocean Dynamics of the Northeastern Atlantic Ocean Across the Marine Isotope Stage 7

AbstractThe upper water‐column dynamics and surface productivity variability in the Northeastern Atlantic Ocean across the Marine Isotope Stage (MIS) 7 interglacial complex is not well understood. Here, we present high‐resolution planktic foraminiferal proxies combined with Artificial Neural Network based‐sea‐surface temperature (SST) and ice‐rafted detritus records from International Ocean Discovery Program Site U1385, SW Iberian Margin for the intervals representing MIS 8 deglaciation, MIS 7 interglacial complex and MIS 6 glacial inception. The long‐term SST pattern is modulated by insolation and precession parameters across the MIS 7 interglacial complex and is superimposed by the millennial‐scale variability (stadials at ∼250, ∼243, ∼230, ∼221, ∼203, ∼196 and ∼192 ka). The regional SST records indicate high temperature gradient (∼6°C) between the sub‐polar North Atlantic Ocean and the SW Iberian Margin during MIS 7d which enhanced the moisture transport from mid‐to‐high latitudes. Further, low obliquity with low insolation induced cooling at high latitudes and promoted the expansion of ice‐sheets during MIS 7d. Comparison of our faunal proxies with the published marine and terrestrial records from SW Europe and western Mediterranean Sea suggested a weakening and southward shift of Azores High (AH) pressure system, similar to the present‐day (−) NAO‐like atmospheric configuration during the early phases of MIS 7e, MIS 7c and MIS 7a, resulting reduced surface productivity of SW Iberian Margin. During the late phases of MIS 7e, MIS 7c and MIS 7a, the AH pressure system strengthened and shifted northward causing the intensification of the trade winds, a scenario similar to present‐day (+) NAO‐like atmospheric configuration, which resulted in high surface productivity of SW Iberian Margin.

Two-stage exhumation of high-pressure rocks by corner flow and mud volcanism within an active subduction zone – A case study from serpentinite mud volcanoes along the Mariana convergent margin

During International Ocean Discovery Program (IODP) Expedition 366 cores were recovered from three serpentinite mud volcanoes containing clasts that originate from the subduction-channel along the Philippine Sea Plate – Pacific Plate boundary. The drilled and sampled mud volcanoes (Yinazao, Fantangisña, and Asùt Tesoru) are located at distances of 55 to 72 km from the Mariana Trench. Mafic rock clasts, embedded within a serpentinite mud matrix, from the flanks and summits of both Asùt Tesoru and Fantangisña Seamounts were analyzed for reconstruction of their metamorphic and deformational overprint in order to reveal the tectono-metamorphic conditions at the metamorphic peak within the subduction channel and the subsequent low-grade overprint during exhumation. Several seamounts comprise clasts of lower plate metabasites with different metamorphic overprint (from low-grade sub-greenschist facies to lower blueschist facies). The metabasites are also associated with clasts of fossiliferous carbonates and cherts with different degrees of metamorphic and deformational overprint, that also originated from the Pacific lower Plate. This implies that these rocks were exhumed from different depths within the subduction channel before being regurgitated within a serpentinite mud matrix. The blueschist facies metamorphic rocks, being affected by metamorphic pressures in the range of 11 to 13.8 kbar at minimum, were very likely exhumed from greater depth within the subduction channel before being captured by uprising, localized serpentinite mudflows, indicating evidence that corner flow is actually taking place along the Mariana convergent margin, and that the high-pressure rocks were exhumed by corner flow in an active subduction zone. Final exhumation, however, is related to the embedding of the rocks within a serpentinite mud matrix and the buoyant ascent of serpentinite mudflows along forearc fracture zones extending from the plate boundary to the upper plate sea floor.

Upper Ocean variations at IODP Hole U1505C in the northern South China Sea and their response to the East Asian Monsoon during the middle Miocene

We used the samples from International Ocean Discovery Program (IODP) Hole U1505C in the northern South China Sea (SCS) to reconstruct the upper ocean profiles and discussed the East Asian Monsoon (EAM) variations during 15.0–12.5 Ma. 15 genera and 41 species were identified, and 7 planktonic foraminifer datums were recognized, then a reliable chronostratigraphic framework was updated. A principal component analysis (PCA) was used to identify the suitable assemblages for reconstructing upper water profiles, based on planktonic foraminifera relative abundance and isotope records. The sea surface temperature (SST), paleo-productivity, and the depth of thermocline (DOT) were reconstructed by the content of warm water species, high productivity species, and the ratio of mixed layer to thermocline species, respectively. Three main phases were identified: (1) during 15.0–14.7 Ma, the SST and paleo-productivity were high, while the thermocline was shallow, indicating a warm and rainy climate influenced by East Asian Summer Monsoon (EASM); (2) during 14.7–13.8 Ma, the SST was lower, the paleo-productivity increased significantly, and the thermocline deepened, indicating an enhanced East Asian Winter Monsoon (EAWM); (3) during 13.8–12.5 Ma, the SST increased slightly, the paleo-productivity deceased, while the DOT showed neglectable change, indicating a stable EAWM and a waning EASM. The results of the Morlet wavelet spectrum revealed that EAM and the upper ocean profiles in the northern SCS were predominantly regulated by the eccentricity cycles, emphasizing the significant impact of low-latitude processes on climate variations.

Apparent Diachroneity of Calcareous Nannofossil Datums During the Early Eocene in the High‐Latitude South Pacific Ocean

AbstractThe late Paleocene to early Eocene interval is characterized by a series of carbon perturbations that caused transient warming (hyperthermal) events, of which the Paleocene‐Eocene Thermal Maximum (PETM) was the largest. These hyperthermals can be recognized in the pelagic sedimentary record as paired negative δ13C and δ18O excursions, in addition to decreased calcium carbonate and increased iron content caused by carbonate dissolution. However, current data are predominantly sourced from the equatorial‐to subequatorial regions. Here we present a new high‐latitude late Paleocene—early Eocene record, recovered during International Ocean Discovery Program (IODP) Expedition 378 on the Campbell Plateau off New Zealand, in the southwest Pacific Ocean. To construct an age model, we correlated our chemostratigraphic and biostratigraphic data to existing astronomically‐tuned age models from Walvis Ridge (South Atlantic Ocean) and Demerara Rise (equatorial Atlantic Ocean). Our results indicate that the Site U1553 composite section spans ∼7 million years of the latest Paleocene to early Eocene (50.5–57.5 Ma), and preserves many of the early Eocene hyperthermals; including a PETM interval that is more expanded than elsewhere in this region. However, construction of the age model also revealed discrepancies between the chemostratigraphic and biostratigraphic tie points used for correlation. This is likely due to latitudinal diachroneity in the calcareous nannofossil biostratigraphic datums, which are primarily based on low‐to mid‐latitude assemblages. Therefore, our study highlights the need to establish a revised calcareous nannofossil biozonation that is more appropriate for high‐latitude age models.

Hazardous explosive eruptions of a recharging multi-cyclic island arc caldera

Caldera-forming eruptions of silicic volcanic systems are among the most devastating events on Earth. By contrast, post-collapse volcanic activity initiating new caldera cycles is generally considered less hazardous. Formed after Santorini’s latest caldera-forming eruption of ~1600 bce, the Kameni Volcano in the southern Aegean Sea enables the eruptive evolution of a recharging multi-cyclic caldera to be reconstructed. Kameni’s eruptive record has been documented by onshore products and historical descriptions of mainly effusive eruptions dating back to 197 bce. Here we combine high-resolution seismic reflection data with cored lithologies from International Ocean Discovery Program Expedition 398 at four sites to determine the submarine architecture and volcanic history of intra-caldera deposits from Kameni. Our shore-crossing analysis reveals the deposits of a submarine explosive eruption that produced up to 3.1 km3 of pumice and ash, which we relate to a historical eruption in 726 ce. The estimated volcanic explosivity index of magnitude 5 exceeds previously considered worst-case eruptive scenarios for Santorini. Our finding that the Santorini caldera is capable of producing large explosive eruptions at an early stage in the caldera cycle implies an elevated hazard potential for the eastern Mediterranean region, and potentially for other recharging silicic calderas.

Highest resolution high signal-to-noise ratio sonic slowness and application to Brothers Volcano, Kermadec Arc, New Zealand

High resolution and accurate acquisition of underground sonic properties is essential for energy detection and earth exploration. An effective method is developed to accurately calculate sonic slowness at the highest resolution (receiver spacing of 0.5 ft) with a high signal-to-noise ratio. The method uses supervirtual interferometry to reconstruct a large number of waveforms for slowness extraction using redundant information from overlapping interreceiver spacing. Synthetic calculations are used to verify the validity of the method, especially in the limited case of strong noise interference and the presence of damaged channels in the array receivers, to accurately calculate the formation of sonic slowness. The theory is applied to process and interpret low data-quality field measurements acquired at Brothers Volcano from the International Ocean Discovery Program. The processing analysis indicates that in the case of very weak formation signals, the residual tool waves from the wireline sonic logging can still interfere with the high-resolution processing, whereas this method can effectively suppress this interference and accurately obtain the formation sonic velocity.

Variations in weathering conditions related to sea level changes during the Albian-Santonian interval in the Western Australian margin as evidenced by clay minerals and Nd/Sr isotopes

The Albian-Santonian interval (∼113–83 Ma) is a key interval for Cretaceous climatic and environmental changes. This interval is associated to a rise in sea level until the Late Cenomanian (∼ 94 Ma) and to a progressive increase in oceanic temperatures, leading to consider the Late Cenomanian-Santonian interval (∼ 94–83 Ma) as the warmest period of the last 200 Myr. While the Albian-Santonian interval has been well studied in the Northern Hemisphere, the climatic and environmental variations and their consequences on weathering conditions are less documented of the Southern Hemisphere, especially in mid and high latitudes. To better understanding the evolution of weathering conditions, associated to continental climate and sea level changes during this key period, an integrated study, based on a coupled mineralogical and geochemical approach, was carried out on the clay-sized (< 2 μm) fraction from sediments of International Ocean Discovery Program Site U1513 (Mentelle Basin, South-western Australia) and Oceanic Drilling Program Site 763 (Carnarvon Basin, North-western Australia). To determinate variations in weathering conditions, the mineral assemblages of the clay fraction was determined by X-ray diffraction and observed for selected samples by electron microscopy. To identify sources of clay minerals, the concentrations of major and selected trace elements, including rare earth elements, together with strontium and neodymium isotopic measurements were performed on the clay-sized fraction. The X-ray diffraction analyses reveal that clay fraction is dominated by R0-type illite/smectite mixed-layers (smectites), followed by variable proportions of illites, kaolinites for both sites and only on Site 763 of palygorskites. These clay minerals are associated with opal and clinoptilolites. Electron microscopy observations have highlighted the dominance of detrital fleecy smectites but also the occurrence of recrystallized lathed smectites and volcanogenic folded smectites for Site U1513, and authigenesis of clay minerals, associated to palygorskites especially on Turonian to Santonian deposits for Site 763. This authigenesis, confirmed by negative cerium anomaly, is also carried by other minerals in the clay-sized fraction (e.g., clinoptilolites, barite). These different authigenic minerals record a seawater-derived isotopic signature. Therefore, isotopic compositions of the clay-sized fraction reflect a mix between a continental contribution, carried by detrital clay minerals and marine one, supported by authigenic minerals, which complicates the identification of sediment sources. However, despite this, our study demonstrates the major influence of sea level variations on mineralogical variations from Albian to Cenomanian in Western margin of Australia. The decrease in kaolinite proportions at Site U1513 from the Albian to the end of the Cenomanian, is probably related to the increase of sea level, which cause a decrease in detrital inputs in the Mentelle Basin associated with a decrease of weathering and drainage conditions. The progressive sea level rise has also enhanced the effect of the differential settling process of clay minerals by the deposition of coarse clays (e.g., kaolinites and illites) on the continental shelf. Kaolinite-bearing clay deposits, derived from the weathering of the Western Australian Craton during the Albian-Cenomanian times, have been progressively substituted from the Turonian by a carbonate sedimentation, for which the terrigenous component consists only of rare detrital and volcanogenic smectites. In Site 763, the occurrence in kaolinite content during the Coniacian would indicate a decrease of differential settling process related to the weathering of the north part of the Western Australia Craton.

Sea-level and monsoonal control on the Maldives carbonate platform (Indian Ocean) over the last 1.3 million years

Abstract. The Maldives Archipelago (Indian Ocean), composed of two rows of atolls that enclose an inner sea, offers an excellent study site to explore the forcings of carbonate production at platforms. Glacial–interglacial sea-level changes have been claimed to be the main factor controlling the carbonate platform factories; however, climatic factors may also have an impact. In this work we used geochemical compositional records, obtained by X-ray fluorescence (XRF) core-scanning from the International Ocean Discovery Program (IODP) Site U1467 in the Maldives Inner Sea, to analyze the orbitally driven fluctuations on the carbonate production and export from the neritic environment into the Maldives Inner Sea over the last 1.3 million years. High Sr aragonite-rich carbonates (HSAC) from neritic settings were deposited in the Maldives Inner Sea during sea-level highstand intervals, increasing the Sr/Ca values. In contrast, low Sr/Ca values are observed coincident with sea-level lowstand periods, suggesting that large areas of the atolls were exposed or unable to grow, and therefore, there was a demise in the carbonate production and sediment export to the Maldives Inner Sea. However, comparison of the Sr/Ca values and the sea-level reconstructions for different interglacial periods before and after the mid-Brunhes event (MBE, ∼ 430 ka) indicates that sea level is not the only factor controlling the production of HSAC during sea-level highstands. The study of monsoon and primary productivity proxies (Fe-normalized, Fe/K, and Br-normalized records) from the same site suggests that the intensity of the summer monsoon and the Indian Ocean dipole probably modulated the carbonate production at the atolls. Moreover, Marine Isotope Stage 11 stands out as a period with high sea level and extraordinary carbonate production in the Maldives platform. This outstanding carbonate production in the Maldives atolls (and in other low-latitude carbonate platforms) probably contributed to the mid-Brunhes dissolution event through a strong shelf-to-basin fractionation of carbonate deposition.

Diagenetic dolomite in planktonic foraminifera on the Australian Northwest Shelf

ABSTRACTPlanktonic foraminiferal shells are widely used to investigate past oceanographic and climatic variations via their trace elements and stable isotopes. However, these geochemical methods may be compromised by the presence of diagenetic high‐Mg calcite. In this study, dolomite crystals are observed in planktonic foraminifera from International Ocean Discovery Program Site U1464 sediments on the Australian Northwest shelf, a shallow marine environment (&lt;300 m). This study investigates the formation of the dolomite using new scanning electron microscopy, X‐ray diffraction, stable isotope (carbon and oxygen), Mg/Ca and rare earth element data, combined with shipboard geochemistry and available literature. This study finds that foraminiferal dolomite formation was probably associated with early diagenesis, microbial and ageing processes. Two potential diagenetic processes (seafloor diagenesis and post‐depositional diagenesis) are proposed, and both indicate that the favourable redox condition of dolomite formation is low oxygen, which may activate methanogenic catalysis to facilitate dolomite formation. It is postulated that high‐Mg calcite may be the precursor of foraminiferal dolomite in this case, and that dissolution–precipitation may be the ageing process of dolomite formation. In contrast to deeper, more normal pelagic environments, this study shows that the marine environment can facilitate dolomite precipitation by higher fluxes of organic matter to the seafloor.

Seawater contamination by coring and pore water sampling of marine sediments

Coring of sediments with minimal physical disturbance, and sampling of pore water with minimal contamination from seawater, are critical in marine geochemistry and microbiology. Yet, sediment coring generally causes smearing of sediment down along the inside of the core liner and leaves seawater and fluid mud trapped around the core. This seawater is a source of diffusive or advective exchange of solutes with the core, which affects the chemistry of retrieved pore water. The exchange depends on the time elapsed between coring and the end of pore water extraction. The degree of seawater contamination is difficult to determine and has generally been neglected in the geochemical literature. Yet, it is possible to quantify seawater contamination due to the high millimolar concentration of sulfate in seawater and low micromolar concentration in the subsurface methanic zone, where sulfate is largely depleted. Analysis of 540 sediment cores from a global database showed that sulfate concentration data beneath the sulfate-methane transition were often truncated and stated as “0” or “0,0” mM, thereby preventing an evaluation of seawater contamination. Among the 181 sediment cores for which the mM sulfate concentrations were reported with two or three decimal places, concentrations measured in methanic sediments were up to an order of magnitude higher than the estimated in situ concentrations in gravity cores and two orders of magnitude higher in cores recovered by scientific ocean drilling. A comparison between pore water extraction by Rhizon suction samplers and by high-pressure squeezers in cores from Baltic Sea Expedition 347 of the IODP (International Ocean Discovery Program) showed no systematic difference in the degree of contamination. A comparison with a perfluorocarbon (PFC) tracer injected by IODP coring into the drilling fluid showed a seawater contamination similar to that based on sulfate in the methanic zone. In IODP cores, where the true in situ sulfate concentration is generally unknown, we calculated the theoretical sulfate concentration that corresponded to equilibrium between SO42−, Ba2+ and barite (BaSO4) to show that the equilibrium sulfate concentrations in the methanic zone are much lower than the sulfate concentrations measured in pore water samples, again indicating seawater contamination. We used a time-resolved diffusion model to calculate how contaminating seawater ions penetrate from the external liner fluid into sediment cores before pore water is extracted. We conclude that nearly all published pore water samples retrieved from subsurface sediments are contaminated by seawater to some degree. We also conclude that sensitive sulfate analyses in methanic sediments constitute a unique opportunity to quantify this contamination and thereby provide a better possibility to control it.

North Atlantic Temperature Change Across the Eocene‐Oligocene Transition From Clumped Isotopes

AbstractThe Eocene‐Oligocene transition (EOT) (∼34 Ma) is marked by the rapid development of a semi‐permanent Antarctic ice‐sheet, as indicated by ice‐rafted debris and a 1–1.5‰ increase in deep sea δ18O. Proxy reconstructions indicate a drop in atmospheric CO2 and global cooling. How these changes affected surface ocean temperatures in the North Atlantic and ocean water stratification remains poorly constrained. In this study, we apply clumped‐isotope thermometry to well‐preserved planktonic foraminifera, that are associated with lower mixed‐layer to subthermocline dwelling depths from the drift sediments at international ocean discovery program Site 1411, Newfoundland, across four intervals bracketing the EOT. The thermocline/lower mixed‐layer dwelling foraminifera record a cooling of 1.9 ± 3.5 K (mean ± 95% CI) across the EOT. While the cooling amplitude is similar to previous sea surface temperature (SST) reconstructions, absolute temperatures (Eocene 20.0 ± 2.9°C, Oligocene 18.0 ± 2.2°C) appear colder than previous organic proxy reconstructions for the northernmost Atlantic extrapolated to this location. We discuss seasonal bias, recording depth, and appropriate consideration of paleolatitudes, all of which complicate the comparison between SST reconstructions and model output. Our subthermocline dwelling foraminifera record a larger cooling across the EOT (Eocene 19.0 ± 3.5°C, Oligocene 13.0 ± 3.2°C, cooling of 5.5 ± 4.6 K) than foraminifera from the thermocline/lower mixed‐layer, consistent with global cooling and an increase in ocean stratification which may be related to the onset or intensification of the Atlantic meridional overturning circulation.

The LILY Database: Linking Lithology to IODP Physical, Chemical, and Magnetic Properties Data

AbstractDuring each expedition of the International Ocean Discovery Program and its precursor, the Integrated Ocean Drilling Program (jointly referred to as IODP), vast arrays of data are collected from drill cores. These data, which are accessible from the IODP LIMS (Laboratory Information Management System) database, include physical, chemical, and magnetic properties collected semi‐continuously along cores using automated track systems, as well as a variety of analyses conducted on discrete subsamples taken from the cores. In addition, the lithology of all cores is described based on visual characteristics of the surface of split cores, visual examination of smear slides and thin sections, and compositional or mineralogical information derived from geochemical analyses. We extract basic lithologic information from this complex array of descriptive information and then tie that information to all other measurements. This new database is referred to as LIMS with Lithology (LILY). LILY currently contains over 34 million data from 89 km of core recovered on 42 expeditions conducted 2009–2019. Some uses of LILY include identifying the abundance of different lithologies, finding data from core intervals with a specific lithology, assessing the efficacy of coring systems in different lithologies, or characterizing and analyzing physical, chemical, and magnetic properties based on lithology. We illustrate the use of LILY by computing the grain density by lithology from over 24,000 moisture and density measurements and then use those grain densities, along with the large IODP bulk density dataset, to compute a new high‐resolution porosity dataset with over 3.7 million new porosity estimates.

Preliminary Characterization of Submarine Basalt Magnetic Mineralogy Using Amplitude‐Dependence of Magnetic Susceptibility

AbstractThe past ∼200 million years of Earth's geomagnetic field behavior have been recorded within oceanic basalts, many of which are only accessible via scientific ocean drilling. Obtaining the best possible paleomagnetic measurements from such valuable samples requires an a priori understanding of their magnetic mineralogies when choosing the most appropriate protocol for stepwise demagnetization experiments (either alternating field or thermal). Here, we present a quick, and non‐destructive method that utilizes the amplitude‐dependence of magnetic susceptibility to screen submarine basalts prior to choosing a demagnetization protocol, whenever conducting a pilot study or other detailed rock‐magnetic characterization is not possible. We demonstrate this method using samples acquired during International Ocean Discovery Program Expedition 391. Our approach is rooted in the observation that amplitude‐dependent magnetic susceptibility is observed in basalt samples whose dominant magnetic carrier is multidomain titanomagnetite (∼TM60–65, (Ti0.60–0.65Fe0.35–0.40)Fe2O4). Samples with low Ti contents within titanomagnetite or samples that have experienced a high degree of oxidative weathering do not display appreciable amplitude dependence. Due to their low Curie temperatures, basalts that possess amplitude‐dependence should ideally be demagnetized either using alternating fields or via finely‐spaced thermal demagnetization heating steps below 300°C. Our screening method can enhance the success rate of paleomagnetic studies of oceanic basalt samples.

Late Miocene to Early Pliocene benthic foraminifera from the Tasman Sea (International Ocean Discovery Program Site U1506)

Abstract. Modern and fossil benthic foraminifera have been widely documented from New Zealand, but detailed studies of material collected from drilling expeditions in the Tasman Sea are scarcer. This study aims to provide an updated taxonomic study for the Late Miocene–Early Pliocene benthic foraminifera in the Tasman Sea, with a specific focus on the paleoceanographic phenomenon known as the Biogenic Bloom. To achieve these goals, we analysed 66 samples from International Ocean Discovery Program (IODP) Site U1506 located in the Tasman Sea and identified a total of 98 taxa. Benthic foraminifera exhibit good preservation, allowing for accurate taxonomic identification. The resulting dataset serves as a reliable and precise framework for the identification and classification of the common deep-water benthic foraminifera in the region. The paleobathymetric analysis based on depth-dependent species indicates deposition at lower bathyal depths. Additionally, the quantitative analysis of the benthic foraminiferal assemblages allowed us to explore their response to the Biogenic Bloom at Site U1506. The paleoenvironmental analysis, focused on the Early Pliocene part of the Biogenic Bloom, points to high-productivity conditions driven by phytoplankton blooms and intensified vertical mixing of the ocean waters. These results provide valuable insights into the paleoceanographic events in the Tasman Sea, particularly the Biogenic Bloom, highlighting the significance of benthic foraminifera as reliable proxies for deciphering paleoenvironmental conditions. The taxonomic identifications and paleoenvironmental interpretations presented herein will aid in future paleoceanographic studies and facilitate comparisons with other deep-sea regions.

Abundance of trace fossil Phycosiphon incertum in core sections measured using a convolutional neural network

A convolutional neural network (CNN) was used to construct a semantic segmentation model to examine the abundance of Phycosiphon incertum by identifying the trace fossil regions in core section images. The abundance of trace fossils provides information about the past activities of benthic animals affected by paleoenvironmental conditions. To quantify the intensity of bioturbation, it is necessary to extract regions of trace fossils and measure the proportion of bioturbated and the observed area of the outcrop section. In this study, a U-Net-type CNN model was used with residual connections and attention mechanisms to identify the trace fossil Phycosiphon. The model was trained to recognize the relationships between core section images from the International Ocean Discovery Program Expedition 362 Site U1480 and manually annotated trace fossil images. After training, the model successfully classified the pixels of the background, outcrop, and Phycosiphon for core section images other than the training data set. The bioturbation intensity estimated from the image predicted by the model was nearly equal to that from the ground truth image. A long-term (approximately past 10 Myr) variation in Phycosiphon abundance was estimated by applying the model to the core section images at Site U1480. Phycosiphon abundance negatively correlated with the number of sandstone layer intercalations, but it was not affected by the sediment accumulation rates. These findings may reflect resistance of Phycosiphon producers to environmental stress. The model developed in this study can be used for other ichnotaxa to reveal the general tendency of variation in bioturbation intensity and ichnodiversity.

Paleocene–Eocene age glendonites from the Mid-Norwegian Margin – indicators of cold snaps in the hothouse?

Abstract. The International Ocean Discovery Program (IODP) Expedition 396 to the mid-Norwegian margin recovered &gt; 1300 m of pristinely preserved, volcanic-ash-rich sediments deposited during the late Paleocene and early Eocene from close to the centre of the North Atlantic Igneous Province (NAIP). Remarkably, many of these cores contain glendonites, pseudomorphs after the purported cold-water mineral ikaite, from sediments dated to the late Paleocene and early Eocene. These time intervals span some of the hottest climates of the Cenozoic, including the Paleocene–Eocene Thermal Maximum (PETM). Global deep-ocean temperatures are not thought to have dropped below 10 ∘C at any point during this time, making the occurrence of supposedly cold-water (near-freezing temperature) glendonite pseudomorphs seemingly paradoxical. This study presents a detailed sedimentological, geochemical, and microscopic study of the IODP Exp. 396 glendonites and presents an updated model for the ikaite-to-calcite transformation for these glendonites. Specifically, we show that early diagenesis of basaltic ashes of the NAIP appear to have chemically promoted ikaite growth in the sediments in this region. Together with existing knowledge of late Paleocene and early Eocene glendonites from Svalbard to the north and early Eocene glendonites from Denmark to the south, these new glendonite finds possibly imply episodic, short-duration, and likely localized cooling in the Nordic Seas region, which may have been directly or indirectly linked to the emplacement of the NAIP.

Evaluation of geomagnetic relative palaeointensity as a chronostratigraphic tool in the Southern Ocean: Refined Plio-/Pleistocene chronology of IODP Site U1533 (Amundsen Sea, West Antarctica)

International Ocean Discovery Program (IODP) Expedition 379 to the Amundsen Sea margin of West Antarctica recovered drill cores at two sites spanning the Latest Miocene–Holocene interval with the aim of reconstructing past West Antarctic Ice Sheet dynamics. The recovered Plio-/Pleistocene sediment sequences offer an opportunity to apply and test different dating approaches in an Antarctic deep-sea drift setting, where the records are nearly continuous and unaffected by scouring of icebergs or grounded ice. Here, through palaeomagnetic analysis of continuous u-channel samples and application of X-ray fluorescence (XRF) scanning, we revise the IODP Exp. 379 Site U1533 age model for the uppermost Pliocene and Pleistocene composite interval (0.0–2.9 Ma). We first refine the magnetostratigraphic age model with high-resolution u-channel analysis and interpreted directional data. Consistent with shipboard results, all major geomagnetic polarity chrons and subchrons are identified in the Pleistocene section. The new high-resolution u-channel dataset also allows us to identify a geomagnetic polarity excursion at ∼884 ka (interpreted as the Kamikatsura excursion) and another excursion at ∼2734 ka with confidence (potentially the Porcupine excursion). Based on the improved polarity stratigraphy, we then develop two new highly resolved age models for Site U1533 using: (i) barium enrichment cycles identified in XRF scanning data, and (ii) geomagnetic relative palaeointensity (RPI). In our first age model, we correlate cyclic variations in sedimentary barium enrichment, inferred to represent changes in export productivity, to glacial‒interglacial cycles of the Lisiecki and Raymo (2005) benthic foraminiferal oxygen isotope (δ18O) stack (LR04). Nearly all Pleistocene Marine Isotope Stages (MIS) are interpreted to be present in the barium enrichment record of Site U1533, assuming simultaneous changes in Antarctic sea-ice extent/local export productivity and global oxygen isotope stratigraphy. We then construct the second, independent age model using the Plio-/Pleistocene RPI record developed for Site U1533, which represents the longest (nearly) continuous RPI record currently available for the Antarctic margin. Comparison of the two, independently derived age models shows a variable offset, on average ± 12 kyr, with the RPI-based ages consistently older than the barium-based ages in the interval from 1.9 to 2.9 Ma and then consistently younger from 0.0 to 1.9 Ma. We interpret these offsets to result from a combination of lock-in depth effects in the younger interval (due to the relatively low sedimentation rates at this site, ∼2 cm/kyr), temporal offsets between global δ18O changes in the deep ocean and productivity response on the Antarctic margin, and/or systematic miscorrelation in the construction of the two age models. Finally, we construct a hybrid age model for the Pleistocene section of Site U1533 by combining a mixture of RPI- and barium-based age tie points that are deemed to be robust. The Site U1533 RPI record is then used, together with other Southern Ocean RPI records, to construct an Antarctic RPI stack (designated as ‘ANT-1600’) for the interval 0.0–1.6 Ma. Although sedimentation rates at two-thirds of the sites selected for the stack are lower than 10 cm/kyr, the new ANT-1600 stack is strongly coherent with the SINT-2000 RPI stack (Valet et al., 2005) on time scales of ∼20–200 kyr, allowing for its use as a regional RPI reference curve in future studies. Overall, we demonstrate that RPI at Antarctic margin/Southern Ocean sites provides a viable and valuable independent dating method for application to Plio-/Pleistocene Antarctic sediments.

A new methodology for foraminifera extraction from cemented calcareous shelf sediments

Choosing the most conservative technique to extract unequivocally identifiable foraminiferal tests is crucial to avoid biases in sedimentary sequence dating and paleoenvironmental interpretations. However, for problematic samples containing heavily encrusted specimens, the concentration and isolation of microfossils might be challenging. In this work, we analyzed Early-Middle Pleistocene samples from the International Ocean Discovery Program (IODP) Site U1460, located on the southwestern Australian shelf platform, characterized by extensive early marine diagenesis. At this site, foraminiferal preservation varies between the glacial and interglacial phases. In particular, tests are highly encrusted in samples representing sea-level lowstands of glacials while exhibiting better preservation in samples corresponding to interglacials. As the application of previously established, very conservative preparation techniques (e.g., sieving technique, soaking in H2O2 solution and gentle sonication) did not produce satisfactory results, it was necessary to set up a new procedure for foraminifera isolation specifically for the cautious cleaning of cemented benthic and planktic foraminiferal tests. This new methodology combines the use of a freeze-dryer with repeated soakings in highly-diluted H2O2 solution to disaggregate the material. To evaluate the efficiency of our technique objectively, we considered the improvements obtained with our procedure on the worst-preserved samples of our record (corresponding to glacials) and the best-preserved (associated with interglacials). Despite being more time-consuming than other preparation techniques, this newly developed procedure produces excellent results in samples exhibiting a high level of encrustation for reliable quantitative studies and isotope analysis on foraminiferal assemblages. Our new methodology is highly conservative and thus preserving even delicate taxa.

Contribution of recycled oceanic crust to the extremely light molybdenum isotopic compositions of mid-ocean ridge basalts from the South China Sea

The contribution of recycled oceanic crust to the mantle source of mid-ocean ridge basalts (MORBs) remains a subject of debate, as radiogenic isotopes alone yield ambiguous insights. Here, we present comprehensive data on whole-rock major element, trace element, and Mo–Nd–Hf isotopic compositions for MORB samples from International Ocean Discovery Program Expedition 349 sites U1431E and U1433B in the eastern (ESB) and southwestern (SWB) subbasins, respectively, of the South China Sea (SCS). The δ98/95Mo values of the SCS MORBs exhibit a significant range (from −0.80‰ to +0.05‰), in contrast to the restricted composition observed in MORBs (δ98/95Mo = −0.19‰ ± 0.01‰). The ESB MORBs display extremely light Mo isotopic compositions (δ98/95Mo = −0.80‰ to −0.24‰) with NdHf isotopic compositions similar to those of Pacific MORB, whereas the SWB MORBs show higher δ98/95Mo values (−0.44‰ to +0.05‰) and depleted NdHf isotopic compositions. The δ98/95Mo values of the SCS MORBs are negatively correlated with Ce/Mo ratios and positively correlated with εHf values, suggesting the incorporation of dehydrated slab components into the source of the SCS MORBs. The subbasin-scale mantle heterogeneity in the SCS can be best explained by varying degrees of interaction between a mantle plume and stagnant slabs in the mantle transition zone, as suggested by mantle tomography. The rigid stagnant slab in the mantle transition zone beneath the SWB largely impeded the upwelling of the mantle plume, whereas the slab beneath the ESB was disrupted by the plume and subsequently transported into the upper mantle. This study, therefore, provides compelling evidence for the involvement of recycled oceanic slabs in generating MORB and the influence of an ascending mantle plume on seafloor spreading in a continental marginal sea. Mantle recycling processes in marginal sea basins exhibit distinct characteristics compared to those occurring in open oceans.